This is the kitchen plan

A good tile installer that knows what he is doing, can easily remove that single piece of tile.... carefully replace it with another one. Do you have another extra pieces of the same tile? Do you know what brand and color the existing grout is? That will be more of the issue trying to get the grout match to match up or the finding the same tile (in the same dye lot) if you need to buy another tile. Did the heat cause the break or did a pan bang into the glass? Consider installing a heat resistant Lumicor or 3 Form panel behind the stove. Any flat material that can be sandwiched between two resin panels. 1). Crushed glass. 2). Fabric. 3). Fabric. 4). Fabric.

Silicon is a soft material and not recommend for sink leakage, better go with Mseal and mix with clear Araldite your sink will b leak proof for next few years.

you have to use pink combination of other colour white as like below