We like to recommend that the grout colour matches the tile as far as possible. This helps to create a seamless effect.

What soft furnishings do you have. You could pic out one or two colours as an accent colour and use that as your Base for the curtains. I currently have cream hessian walls and have a duck egg blue and chocolate curtains. I'm currently making matching Oxford cushion covers for the settees . If you can't find what your looking for ready made buy the fabric and have bespoke curtains made for you.

I'd suggest dark red curtains if you need curtains at all -- the windows are beautiful as they are, and I'm not sure whether some kind of blind might not give you the ability to darken the room when you want to. On the wall, if you are real fans of any movies or TV shows, three big posters would be fun. Otherwise, I would still suggest using three pieces of art there of that size, all equal in size and somehow relating to each other. Three floral works, or three works in the same style, perhaps. I think a large plain textured rug in a light neutral from one of the cushion fabrics would tie the space together well. You might also consider a lovely low coffee table on the rug to lay out your snacks and drinks for serious media nights.

I prefer shades of brown ..blends well with all colors.